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If you specifically wanted (the 1v1 fighting game with the Sasuke vs Killer Bee boss fight), you cannot play it on PPSSPP . You would need a PS3 emulator (like RPCS3 on PC) or an actual PS3/Xbox 360.
If you find a "zip" file for this game on PPSSPP, it is likely one of the following fan-made projects: Naruto Shippuden: Ultimate Ninja Impact (Modded) naruto shippuden ultimate ninja storm 2 ppsspp zip file
However, there is a popular of the official PSP game Naruto Shippuden: Ultimate Ninja Impact that skins the game to look and feel like Storm 2 for use on the PPSSPP emulator . How the "Storm 2 PPSSPP" Mod Works If you specifically wanted (the 1v1 fighting game
The game features a vast array of characters from the Naruto universe, including the main protagonist Naruto Uzumaki and his friends, as well as some of his strongest foes. The gameplay involves one-on-one fighting, with players using a combination of physical attacks, jutsu (ninja techniques), and items to defeat their opponents. How the "Storm 2 PPSSPP" Mod Works The